What is free radical addition polymerization?

What is free radical addition polymerization?

Definition. A process forming a polymer from a monomer is termed “polymerization.” When unsaturated monomers undergo chain polymerization involving free radicals as a chain carrier, the process refers to “free-radical addition polymerization” or simply “radical polymerization.”

What are the steps in radical polymerization?

There are three general stages of free radical polymerization: 1) initiation, 2) propagation, 3) termination.

What are the 3 stages of polymerization?

The polymerization reaction consists of three stages: (1) initiation, (2) propagation, and (3) termination.

What is meant by addition polymerization?

In polymerization. In addition polymerization, monomers react to form a polymer without the formation of by-products. Addition polymerizations usually are carried out in the presence of catalysts, which in certain cases exert control over structural details that have important effects on the properties of the polymer.

What is radical polymerization explain with examples?

Free-radical polymerization is a type of chain-growth polymerization, along with anionic, cationic and coordination polymerization. IUPAC definition. A chain polymerization in which the kinetic-chain carriers are radicals. Note: Usually, the growing chain end bears an unpaired electron.

What is addition polymerization explain the mechanism of addition polymerization?

1 Addition Polymerization. In addition polymerization (sometimes called chain-growth polymerization), a chain reaction adds new monomer units to the growing polymer molecule one at a time through double or triple bonds in the monomer.

How does raft polymerisation work?

RAFT is a type of living polymerization involving a conventional radical polymerization which is mediated by a RAFT agent. Monomers must be capable of radical polymerization. There are a number of steps in a RAFT polymerization: initiation, pre-equilibrium, re-initiation, main equilibrium, propagation and termination.

What are the 4 steps of polymerization?


  • Addition Polymerisation.
  • Initiation. The polymerisation reaction is initiated through the addition of a free radical.
  • Propagation. Following initiation, the process continues with the successive addition of monomer units to the chains.
  • Termination.

What is the process of polymerization?

polymerization, any process in which relatively small molecules, called monomers, combine chemically to produce a very large chainlike or network molecule, called a polymer. The monomer molecules may be all alike, or they may represent two, three, or more different compounds.

What is addition polymerization shaala?

Solution 2 Addition polymerization is the process of repeated addition of monomers, possessing double or triple bonds to form polymers. For example, polythene is formed by addition polymerization of ethene.

What is addition polymerization give two examples?

Examples- Polyethylene, Polyvinyl Chloride, Teflon, Rubbers (Buna-N, Buna-S), Polyacrylonitrile. In this reaction, n molecules of tetrafluoroethylene are polymerized to form Teflon.